That would not be appropriate to calibrate an auto titrator. Note firstly that ”a grade glassware” is not a Certified Reference material. The glassware does not come with an individual calibration certificates.
Your equipment supplier or equipment manual should provide you with suitable information, Simply stated, you would need to use a suitable balance and determine the volume dispensed gravimetrically; or use a primary standard for titration to determine the linearity and correlation coefficient of the auto titrator. Depending on the methods you use, you would select a suitable primary standard and titrate a range of five quantities as per your method to provide data for the calculations.