ISO 17025 clauses

You asked

"Which management team centric clauses require processes set up early in all cases, which can wait?

It is effective to establish organisational structure (clause 5), personnel roles and responsibilities (clause 5 and 6.2), quality policies (clause 8.2) and document and record control (clause 8.3, 8.4) upfront.

You also asked

Also which significant clauses/ groups of clauses do existing test houses adopting 17025 have most issues implementing suitably, so need most care/ time to develop, to get right first time?

Besides the performance of methods in term of method validations, attention and time should be allocated to Personnel (clause 6.2) requirements and  Equipment (clause 6.4) requirements as there a large number of evaluations and record-keeping involved.

For more information see my reply to another question https://community.advisera.com/topic/common-challenges-in-accreditation-process/